2-Hydroxyalkyl Diphenylphosphines: Biocatalytic Resolution and Use as Ligands for Transition-metal Catalysts

DOI: 10.1016/S0040-4039(00)79437-8

Source and publish data:

Tetrahedron Letters p. 5959 - 5962 (1991)

Update date:2022-08-04

Topics:

Authors:

Kagan, Henri B.

Tahar, Maurice

Fiaud, Jean-Claude

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79437-8

Kinetic resolution of 2-hydroxyalkyldiphenylphosphines 1 by acylation with isopropenyl acetate was carried out under rabbit gastric lipase (RGL) catalysis to give optically active 1 and the corresponding acetate, the enantioselectivity factors E ranging from 10 to 20. Key words: 2-hydroxyalkyldiphenylphosphines; rabbit gastric lipase; kinetic resolution; biocatalysis; acylation

Full text of DOI:10.1016/S0040-4039(00)79437-8

Products guided by the article

Product name:2-Propanol, 1-(diphenylphosphino)-, acetate (ester), (R)-

Cas No:138056-28-7

R&D Labs maybe for 138056-28-7

Shanghai Cheerchem Co., Ltd.

Contact:86-21-50966856

Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
shijiazhuang baisheng chem co.; ltd

Contact:86-0311-80790826

Address:shijiazhuang hebei
X.T.Y Environ-Tech Co.,Ltd

Contact:+86-310-7092106

Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Kono Chem Co.,Ltd

website:http://www.konochem.com

Contact:86-29-86107037

Address:No.170 West Avenue,Xi’an 710082,China

Relevant to this article

The bioactive conformation of aminoalkylindoles at the cannabinoid CB1 and CB2 receptors: Insights gained from (E)- and (Z)-naphthylidene indenes

Doi:10.1021/jm9801197
(1998)
Enantioselective catalysis; 123: Octaaldehyde type chelating ligands - A divergent synthesis approach to easily tunable expanded ligands for enantioselective catalysis

Doi:10.1055/s-1998-2226
(1998)
Novel pyridine-formation reactions of 2-(phosphoranylideneamino)acrylaldehydes with acetylenic esters. Synthesis of 2-mono-and 2,5-disubstituted nicotinates

Doi:10.3987/COM-98-8314
(1998)
Chiral Phosphorus-Olefin Ligands for the Rh^I-Catalyzed Asymmetric Addition of Aryl Boronic Acids to Electron-Deficient Olefins

Doi:10.1002/asia.201600143
(2016)
Synthesis and biological evaluation of an orally active ghrelin agonist that stimulates food consumption and adiposity in rats

Doi:10.1016/j.bmcl.2004.09.027
(2004)
Dynamic Molecular Invasion into a Multiply Interlocked Catenane

Doi:10.1002/anie.201708248
(2017)

Article Doi