2-Hydroxyalkyl Diphenylphosphines: Biocatalytic Resolution and Use as Ligands for Transition-metal Catalysts

DOI: 10.1016/S0040-4039(00)79437-8

Source and publish data:

Tetrahedron Letters p. 5959 - 5962 (1991)

Update date:2022-08-04

Topics:

Authors:

Kagan, Henri B.

Tahar, Maurice

Fiaud, Jean-Claude

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Article abstract of DOI:10.1016/S0040-4039(00)79437-8

Kinetic resolution of 2-hydroxyalkyldiphenylphosphines 1 by acylation with isopropenyl acetate was carried out under rabbit gastric lipase (RGL) catalysis to give optically active 1 and the corresponding acetate, the enantioselectivity factors E ranging from 10 to 20. Key words: 2-hydroxyalkyldiphenylphosphines; rabbit gastric lipase; kinetic resolution; biocatalysis; acylation

Full text of DOI:10.1016/S0040-4039(00)79437-8

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