Diastereoselectivity in the Cyclopropanation of 3,3-Bimetallic Allylic Alcohols. Preparation of Diastereomeric Cyclopropyl Carbinols via a Simple Oxidation-Reduction Sequence

DOI: 10.1021/jo00113a031

Source and publish data:

Journal of Organic Chemistry p. 2474 - 2487 (1995)

Update date:2022-07-29

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Authors:

Lautens, Mark

Delanghe, Patrick H. M.

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Article abstract of DOI:10.1021/jo00113a031

A highly diastereoselective cyclopropanation of allylic alcohols, containing a silyl and/or stannyl group using samarium/dihalomethane, provides a variety of bimetallic cyclopropane carbinols in good yield.A comparison with the more traditional Simmons-Sm

Full text of DOI:10.1021/jo00113a031

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