Stoichiometric and catalytic hydroamination of alkynes and allene by zirconium bisamides Cp2Zr(NHR)2

DOI: 10.1021/ja00031a026

Source and publish data:

Journal of the American Chemical Society p. 1708 - 1719 (1992)

Update date:2022-08-04

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Authors:

Walsh, Patrick J.

Baranger, Anne M.

Bergman, Robert G.

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Article abstract of DOI:10.1021/ja00031a026

We have found that the bisamides Cp₂Zr(NHR)₂ (1) catalyze the hydroamination of alkynes and allene and have investigated the scope and mechanism of this process. Examining both catalytic and stoichiometric additions of 2,6-dimethylan

Full text of DOI:10.1021/ja00031a026

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Product name:(C₅H₅)2Zr(N(C₆H₃(CH₃)2)C(C₆H₅)CH(C₆H₅))(NHC₆H₃(CH₃)2)

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