Application of efficient glycosylation of 2,6-anhydro-2-thio sugar to the total synthesis of erythromycin A

DOI: 10.1016/0040-4039(91)80777-4

Source and publish data:

Tetrahedron Letters p. 6155 - 6158 (1991)

Update date:2022-07-30

Topics:

Authors:

Toshima Toshima

Mukaiyama

Yoshida Yoshida

Tamai Tamai

Tatsuta Tatsuta

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Article abstract of DOI:10.1016/0040-4039(91)80777-4

The total synthesis of erythromycin A (1) from (9S)-9-dihydroerythronolide A (2) was achieved efficiently by the highly stereoselective and powerful glycosylation of 2,6-anhydro-2-thio sugar 9 as a key step.

Full text of DOI:10.1016/0040-4039(91)80777-4

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Product name:(9S)-9-dihydro-3,5-O-(p-methoxybenzylidene)erythronolide A

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