Metalation reactions. XV. Regioselective metalation of (alkylthio)fluorobenzene

DOI: 10.1016/0022-328X(91)86159-N

Source and publish data:

Journal of Organometallic Chemistry p. 1 - 8 (1991)

Update date:2022-08-05

Topics:

Authors:

Cabiddu, S.

Fattuoni, C.

Floris, C.

Gelli, G.

Melis, S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(91)86159-N

In reactions of (alkylthio)fluorobenzenes with n-butyllithium the compounds 4-RSC6H4F (R = Me, ⁱPr) and 2-ⁱPrSC6H4F were found to undergo metalation selectively ortho to the fluorine atom, whereas 2-MeSC6H4F undergoes metalation at the thiomethyl carbon atom.

Full text of DOI:10.1016/0022-328X(91)86159-N

Products guided by the article

Product name:Benzoic acid, 2-fluoro-3-[(1-methylethyl)thio]-

Cas No:138736-67-1

R&D Labs maybe for 138736-67-1

ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
PharmOrgsyn

Contact:+86-21-38228826

Address:Room 505 Building 2, No 3377 Kangxin Highway, Shanghai, Republic China
Chengdu Green Young Biopharmaceutical INC

Contact:+86-28-85337952

Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000
SHAANXI TOP PHARM CHEMICAL CO.LTD

Contact:+86-029-85733403

Address:No.108 ,west sector,south er huan,xi'an,china
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China

Relevant to this article

Magnetic CuO nanoparticles supported on graphene oxide as an efficient catalyst for A³-coupling synthesis of propargylamines

Doi:10.1016/j.cclet.2015.05.021
(2015)
Accessibility and selective stabilization of the principal spin states of iron by pyridyl versus phenolic ketimines: Modulation of the ⁶ A ₁ ? ² T ₂ ground-state transformation of the [FeN₄O₂]⁺ chromophore

Doi:10.1021/ic300732r
(2012)
Synthesis of some novel fused imidazo [2, 1-b] [1, 3] thiazole and imidazo [2, 1-b] thiazolo [5, 4-d] isoxazole derivatives

Doi:10.1155/2012/896454
(2012)
Rhodium(iii)-catalyzed oxidative mono- and di-olefination of isonicotinamides

Doi:10.1039/c2ob25773d
(2012)
Stereoselective synthesis of both half segments for (-)-sarcophytonin A and (-)-sarcophytoxide

Doi:10.1248/cpb.39.2514
(1991)
Substituent effect in reaction of dicyclohexylcarbodiimide with substituted benzoic acids

Doi:10.1016/0040-4020(95)00400-3
(1995)

Article Doi