Metalation reactions. XV. Regioselective metalation of (alkylthio)fluorobenzene

DOI: 10.1016/0022-328X(91)86159-N

Source and publish data:

Journal of Organometallic Chemistry p. 1 - 8 (1991)

Update date:2022-08-05

Topics:

Authors:

Cabiddu, S.

Fattuoni, C.

Floris, C.

Gelli, G.

Melis, S.

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Article abstract of DOI:10.1016/0022-328X(91)86159-N

In reactions of (alkylthio)fluorobenzenes with n-butyllithium the compounds 4-RSC6H4F (R = Me, ⁱPr) and 2-ⁱPrSC6H4F were found to undergo metalation selectively ortho to the fluorine atom, whereas 2-MeSC6H4F undergoes metalation at the thiomethyl carbon atom.

Full text of DOI:10.1016/0022-328X(91)86159-N

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