Stereoselective synthesis of (E) or (Z) α-alkenylphosphonates via α-stannylated phosphonates

Article abstract of DOI:10.1080/00397919108021594

α-lithiostannylalkylphosphonates react with aldehydes with the complete elimination of the organotin moiety. The stereoselective formation of the (E) or (Z) α-alkenylphosphonates is closely dependent on the tin substituent.

Full text of DOI:10.1080/00397919108021594

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Synthetic Communications:
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Stereoselective
Synthesis of (E) or (Z) α-
Alkenylphosphonates via α-
Stannylated Phosphonates
N. Mimouni a , E. About-Jaudet a , N. Collignon a
& Ph. Savignac b
a Laboratoire des Composés organophosphorés
INSA-IRCOF , BP 08, 76131, Mont-Saint-Aignan,
Cedex, (France)
b Laboratoire de Chimie du Phosphore et
des Métaux de Transition DCPH - Ecole
Polytechnique , 91128, Palaiseau, Cedex,
(France)
Published online: 23 Sep 2006.
To cite this article: N. Mimouni , E. About-Jaudet , N. Collignon & Ph. Savignac
(1991) Stereoselective Synthesis of (E) or (Z) α-Alkenylphosphonates via α-
Stannylated Phosphonates, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 21:22, 2341-2348, DOI:
10.1080/00397919108021594
To link to this article: http://dx.doi.org/10.1080/00397919108021594
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