
Bulletin of the Chemical Society of Japan p. 3411 - 3416 (1991)
Update date:2022-07-29
Topics:
Tamagaki, Seizo
Mimura, Takashi
Tagaki, Waichiro
The HClO4-catalyzed H2O2- and O2-oxidations of a dihydropyridine in acetonitrile were mechanistically investigated; the H2O2-oxidation under nitrogen followed a heterolytic course to yield the corresponding pyridinium salt along with a monooxygenated product, while the O2-oxidation produced the pyridinium salt and H2O2 via a radical-chain pathway in which H2O2 is not only merely the product but also an initiator.
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