
Tetrahedron Letters p. 7009 - 7012 (1991)
Update date:2022-08-03
Topics:
Folkins, Patricia L.
Vincent, Beverly R.
Harpp, David N.
The generation of a pseudo-diatomic species "R.P=S" (thioxophosphane) has been achieved from the reaction of triphenyldibromophosphorane (4) with bis(triphenylmethylmercapto)phosphines (7). This reactive intermediate was trapped via Diels-Alder addition to 1,3-dienes producing cyclic thiophosphoranes 13, 15, 16 and 18 along with two acyclic species, 14 and 17.
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