The First Stable Aldehyde and Ketone Complexes of Zinc: the Structure of t3)2(p-O=CHC6H4OMe)>2

DOI: 10.1039/c39910001735

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1735 - 1737 (1991)

Update date:2022-08-06

Topics:

Authors:

Bochmann, Manfred

Webb, Kevin J.

Hursthouse, Michael B.

Mazid, Muhammed

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Article abstract of DOI:10.1039/c39910001735

The reaction of Zn(EC6H2Bu^t3)2 (E = S or Se) with organic carbonyl compounds gives the first isolable aldehyde and ketone complexes of zinc as models for transient metal-substrate complexes in metalloenzymes such as liver alcohol dehydrogenase.

Full text of DOI:10.1039/c39910001735

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