Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis; 2. Incubation and interpretation

DOI: 10.1016/0040-4020(95)01072-6

Source and publish data:

Tetrahedron p. 2537 - 2556 (1996)

Update date:2022-07-30

Topics:

Authors:

Baldwin, Jack E.

Adlington, Robert M.

Marquess, Daniel G.

Pitt, Andrew R.

Porter, Michael J.

Russell, Andrew T.

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Article abstract of DOI:10.1016/0040-4020(95)01072-6

Evidence to support an insertion-homolysis mechanism for the event leading to carbon-sulphur bond formation in penicillin biosynthesis has been obtained by incubation of a series of cyclopropane-containing stereochemical probes.

Full text of DOI:10.1016/0040-4020(95)01072-6

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