A facile cyclopropanol synthesis from β-halo ester with Grignard reagent-samarium(II) diiodide couple

DOI: 10.1016/0040-4039(91)80567-P

Source and publish data:

Tetrahedron Letters p. 7691 - 7694 (1991)

Update date:2022-08-04

Topics:

Authors:

Fukuzawa

Niimoto Niimoto

Sakai Sakai

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80567-P

Transformation of α,β-halo ester to the cyclopropanols by a coupled reagent of samarium(II) diiodide with Grignard reagent in tetrahydrofuran-hexamethylphosphoric triamide was very successful under mild conditions.

Full text of DOI:10.1016/0040-4039(91)80567-P

Products guided by the article

Product name:Silane, [(1-cyclohexylcyclopropyl)oxy]trimethyl-

Cas No:139336-65-5

R&D Labs maybe for 139336-65-5

Suzhou CarbonWell Pharma-Tech Co., Ltd

Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602

Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200
ZIBO GREEN TRADE CO., LTD

Contact:0543-3317184

Address:No.1401, Unit 1, Global building, Binzhou city, shandong PRC.
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province

Relevant to this article

Highly concise and stereoselective total synthesis of (5R,7S)-kurzilactone

Doi:10.1002/hlca.201100466
(2012)
N-1-Alkyl-2-oxo-2-aryl amides as novel antagonists of the TRPA1 receptor

Doi:10.1016/j.bmcl.2012.07.032
(2012)
3-(3,4-dihydroisoquinolin-2(1 H)-ylsulfonyl)benzoic acids: Highly potent and selective inhibitors of the type 5 17-β-hydroxysteroid dehydrogenase AKR1C3

Doi:10.1021/jm3007867
(2012)
Phosphine adducts of 1,2-dibromo-1,2-dimesityldiborane(4): Between bridging halides and rearrangement processes

Doi:10.1002/anie.201201673
(2012)
Copper-catalyzed desymmetric intramolecular Ullmann C-N coupling: An enantioselective preparation of indolines

Doi:10.1021/ja306631z
(2012)
Doi:10.1016/S0040-4020(01)93408-8
(1973)

Article Doi