Reactions at highly sterically hindered organosilicon centres. Chemistry of (Me3Si)3CSiPhHI, (Me3Si)3CSiPh(OMe)I, and related species

Article abstract of DOI:10.1016/0022-328X(91)86400-K

The iodide TsiSiPhHI (Tsi = (Me3Si)3C) has been shown to react with a range of silver(I) salts, AgY, to give the corresponding species TsiSiPhHY; the reactions with AgOCN give either the isocyanate alone or a mixture of this with the normal cyanate, depen