Reactions at highly sterically hindered organosilicon centres. Chemistry of (Me3Si)3CSiPhHI, (Me3Si)3CSiPh(OMe)I, and related species

DOI: 10.1016/0022-328X(91)86400-K

Source and publish data:

Journal of Organometallic Chemistry p. 159 - 169 (1991)

Update date:2022-08-05

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Authors:

Aiube, Zakariah H.

Eaborn, Colin

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Article abstract of DOI:10.1016/0022-328X(91)86400-K

The iodide TsiSiPhHI (Tsi = (Me3Si)3C) has been shown to react with a range of silver(I) salts, AgY, to give the corresponding species TsiSiPhHY; the reactions with AgOCN give either the isocyanate alone or a mixture of this with the normal cyanate, depen

Full text of DOI:10.1016/0022-328X(91)86400-K

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