Copper-mediated alkylation of vitamin DC-ring. Synthesis of C11-functionalized 1α,25-dihydroxyvitamin D3

DOI: 10.1016/S0040-4020(97)00692-3

Source and publish data:

Tetrahedron p. 10851 - 10870 (1997)

Update date:2022-08-04

Topics:

Authors:

Torneiro, Mercedes

Fall, Yagamare

Castedo, Luis

Mourino, Antonio

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Article abstract of DOI:10.1016/S0040-4020(97)00692-3

This work describes our studies on the functionalization at C11 of CD-ring fragments of vitamin D₃ using organocopper reagents. As an application, an efficient, convergent synthesis of 11α-[3,3-(dimethoxy)propyl] calcitriol analogue 2, which ma

Full text of DOI:10.1016/S0040-4020(97)00692-3

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