The regioselective synthesis of enantiomerically pure myo-inositol derivatives. Efficient synthesis of myo-inositol 1,4,5-trisphosphate

DOI: 10.1016/S0040-4039(00)74142-6

Source and publish data:

Tetrahedron Letters p. 401 - 404 (1992)

Update date:2022-08-03

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Authors:

Aguilo, Agustin

Martin-Lomas, Manuel

Penades, Soledad

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Article abstract of DOI:10.1016/S0040-4039(00)74142-6

Regioselective 1-O-acylation of myo-inositol and simultaneous optical resolution has been achieved by perborylation, transmetallation using di-n-butyltin-bis-acetylacetonate and then acylation with (-)-menthyl chloroformate. Diastereomerically pure 1-O-(-

Full text of DOI:10.1016/S0040-4039(00)74142-6

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Product name:1-O-menthoxycarbonyl-2,3:5,6-di-O-isopropylidene-myo-inositol

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