Tetrahedron Letters p. 213 - 216 (1992)
Update date:2022-08-03
Topics:
Nohair, Khaddouj
Lachaise, Isabelle
Paugam, Jean-Paul
Nedelec, Jean-Yves
Free-radical chain addition of various polyhalomethanes onto olefins can be easily initiated by electrochemically in situ generated manganic salt used in catalytic amount associated with an equimolar amount of a Mn(III)-oxidizable compound like methyl cyano- or aceto-acetate.Key Words: Radical addition reactions; Manganic salt; Electrochemistry
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