Mn(III)-Mediated Electrochemical C,C-Bond Formation: Radical Addition of Polyhalomethanes to Olefins

DOI: 10.1016/0040-4039(92)88053-8

Source and publish data:

Tetrahedron Letters p. 213 - 216 (1992)

Update date:2022-08-03

Topics:

Authors:

Nohair, Khaddouj

Lachaise, Isabelle

Paugam, Jean-Paul

Nedelec, Jean-Yves

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Article abstract of DOI:10.1016/0040-4039(92)88053-8

Free-radical chain addition of various polyhalomethanes onto olefins can be easily initiated by electrochemically in situ generated manganic salt used in catalytic amount associated with an equimolar amount of a Mn(III)-oxidizable compound like methyl cyano- or aceto-acetate.Key Words: Radical addition reactions; Manganic salt; Electrochemistry

Full text of DOI:10.1016/0040-4039(92)88053-8

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