Aryl Halides as Convenient Precursors of Electrogenerated Bases. Efficient Syntheses of β-Oxo Nitriles or Esters by Coupling Active-hydrogen Groups with Esters

DOI: 10.1039/c39920000050

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 50 - 51 (1992)

Update date:2022-07-31

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Authors:

Barhdadi, Rachid

Gal, Jacques

Heintz, Monique

Troupel, Michel

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Article abstract of DOI:10.1039/c39920000050

In an undivided cell fitted with a sacrificial anode and a nickel cathode on which cadmium had been deposited, the electroreduction of aromatic halides affords a strong base which allows the effective synthesis of β-oxo nitriles or β-oxo esters from the coupling of active-hydrogen compounds with esters.

Full text of DOI:10.1039/c39920000050

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