Stereochemically controlled competitive cyclisations with phenylthio migration in the synthesis of cyclic ethers

DOI: 10.1016/S0040-4039(00)93990-X

Source and publish data:

Tetrahedron Letters p. 539 - 542 (1992)

Update date:2022-07-29

Topics:

Authors:

Sansbury

Warren Warren

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Article abstract of DOI:10.1016/S0040-4039(00)93990-X

Two primary alcohol groups attached by carbon chains to the same carbon atom complete in cyclisation to an episulphonium ion during acid-catalysed phenylthio migration. The anti product is formed exclusively even when this involves chemoselectivity betwee

Full text of DOI:10.1016/S0040-4039(00)93990-X

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Product name:3-Hydroxy-2-hydroxymethyl-3-(1-phenylsulfanyl-cyclohexyl)-propionic acid ethyl ester

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