Profound Catalyst Effects in the Generation and Reactivity of Carbenoid-Derived Cyclic Ylides

DOI: 10.1021/jo00102a007

Source and publish data:

Journal of Organic Chemistry p. 6892 - 6894 (1994)

Update date:2022-08-02

Topics:

Authors:

West, F. G.

Naidu, B. N.

Tester, Richland W.

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Article abstract of DOI:10.1021/jo00102a007

In contrast to results with Rh2(OAc)4, good yields of ylide-derived <1,2>-shift (or in some cases <1,4>-shift) products were obtained upon treatment of amino diazo ketone substrates 3b,c and alkoxy diazo ketone substrates 5b,c with soluble Cu(II) catalyst

Full text of DOI:10.1021/jo00102a007

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