"Syn-Effect" in the Conversion of (E)-Vinylic Sulfones to the Corresponding Allylic Sulfones

DOI: 10.1246/bcsj.65.75

Source and publish data:

Bulletin of the Chemical Society of Japan p. 75 - 96 (1992)

Update date:2022-07-29

Topics: Conversion Experimental terms Allylic sulfones

Authors:

Hirata, Takaki

Sasada, Yoshihiro

Ohtani, Takashi

Asada, Takahiro

Kinoshita, Hideki

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.65.75

It was found that (E)-vinylic sulfones preferentially afford (Z)-allylic sulfones as kinetically-controlled products by treatment with a base under mild conditions, while (Z)-vinylic sulfones give (E)-allylic sulfones.Such stereochemical relationship was

Full text of DOI:10.1246/bcsj.65.75

Products guided by the article

Product name:Benzene, 1-[(3-chloro-1-pentenyl)sulfonyl]-4-methyl-, (E)-

Cas No:139951-07-8

R&D Labs maybe for 139951-07-8

Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China
Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Wuhan Konberd Biotech Co., Ltd.

Contact:+86-27-87205925

Address:NO.666, Gaoxin Road, Eastlake High-tech zone

Relevant to this article

Quantum chemistry-based interpretations on the lowest triplet state of luminescent lanthanides complexes. Part 1. Relation between the triplet state energy of hydroxamate complexes and their luminescence properties

Doi:10.1039/b316246j
(2004)
Molecular docking studies, in vitro-brine shrimp lethal assay and antibacterial assessment of embelin, vilangin and phenyl vilangin against endodontic pathogen, Enterococcus faecalis

Doi:10.1007/s11164-021-04559-8
(2021)
Acetic acid promoted metal-free aerobic carbon-carbon bond forming reactions at α-position of tertiary amines

Doi:10.1021/ol5018883
(2014)
Diastereoselective reduction of β-keto carbonyl compounds by cultured plant cells

Doi:10.1016/j.tetlet.2006.01.005
(2006)
Structure-based design of 2-aminopyridine oxazolidinones as potent and selective tankyrase inhibitors

Doi:10.1021/ml4003315
(2013)
Synthesis of 3′-azido-2′,3′-dideoxy-5-fluorouridine phosphoramidates and evaluation of their anticancer activity

Doi:10.1016/j.ejmech.2013.06.047
(2013)

Article Doi