"Syn-Effect" in the Conversion of (E)-Vinylic Sulfones to the Corresponding Allylic Sulfones

DOI: 10.1246/bcsj.65.75

Source and publish data:

Bulletin of the Chemical Society of Japan p. 75 - 96 (1992)

Update date:2022-07-29

Topics: Conversion Experimental terms Allylic sulfones

Authors:

Hirata, Takaki

Sasada, Yoshihiro

Ohtani, Takashi

Asada, Takahiro

Kinoshita, Hideki

et al. et al.

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Article abstract of DOI:10.1246/bcsj.65.75

It was found that (E)-vinylic sulfones preferentially afford (Z)-allylic sulfones as kinetically-controlled products by treatment with a base under mild conditions, while (Z)-vinylic sulfones give (E)-allylic sulfones.Such stereochemical relationship was

Full text of DOI:10.1246/bcsj.65.75

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