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Total synthesis of furanocembranolides. 2. Macrocyclization studies culminating in the synthesis of a dihydropseudopterolide and gorgiacerone. Related furanocembranolide interconversions

DOI: 10.1021/ja00036a046

Source and publish data:

Journal of the American Chemical Society p. 3926 - 3936 (1992)

Update date:2022-08-04

Topics: Total synthesis   Macrocyclization   Interconversions  

Authors:

RaynerRayner

AstlesAstles

PaquettePaquette

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Article abstract of DOI:10.1021/ja00036a046

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Full text of DOI:10.1021/ja00036a046

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Product name:5-((R)-1-{(R)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-oxo-2,5-dihydro-furan-2-yl}-2-methyl-allyl)-2-[(Z)-3-methyl-4-(tetrahydro-pyran-2-yloxy)-but-2-enyl]-furan-3-carboxylic acid methyl ester

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