Direct transformation of secondary amides into secondary amines: Triflic anhydride activated reductive alkylation

DOI: 10.1002/anie.201204098

Source and publish data:

Angewandte Chemie - International Edition p. 8314 - 8317 (2012)

Update date:2022-07-30

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Authors:

Xiao, Kai-Jiong

Wang, Ai-E

Huang, Pei-Qiang

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Article abstract of DOI:10.1002/anie.201204098

Versatile and mild: The first general method for the title transformation has been developed (see scheme; 2-F-Py=2-fluoropyridine; Tf=trifluorosulfonyl). The amines are synthesized in good yields and the ketimine intermediates can be isolated before the r

Full text of DOI:10.1002/anie.201204098

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