Nucleophilic Desulfinylation of α-Fluoro-β-(alkoxy and silyloxy) Sulfoxides. Effects of the β-Oxy Substituent on Protonation, 1,2-Hydrogen Migration, and Nucleophile Addition to the Fluorocarbenoid Centers

DOI: 10.1246/bcsj.65.218

Source and publish data:

Bulletin of the Chemical Society of Japan p. 218 - 227 (1992)

Update date:2022-07-29

Topics:

Authors:

Uno, Hidemitsu

Sakamoto, Katsuji

Suzuki, Hitomi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.65.218

Treatment of 2-(4-biphenylyl)-2-t-butyldimethylsilyloxy-1-chloro-1-fluoroethyl phenyl sulfoxide with PhMgBr resulted in the formation of a fluorostilbene derivative, a fluoro enol silyl ether and small amounts of 4-(fluoroacetyl)biphenyl, while a similar

Full text of DOI:10.1246/bcsj.65.218

Products guided by the article

Product name:2-(t-butyldimethylsilyloxy)-1-chloro-1-fluoro-4-phenylbutane

Cas No:140156-48-5

R&D Labs maybe for 140156-48-5

Shanghai Bojing Chemical Co., Ltd.

Contact:021-37122233

Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Beijing Top Science biological technology co., LTD

Contact:+86-13439059536

Address:15-1705 jre three mile, Beijing 100000,CHINA
Jiangsu Fengshan Group Co., Ltd.

Contact:86-25-86558671

Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China
Goldwills Pharmaceuticals Co., Ltd.

Contact:0916-2237889 13991621155

Address:North Suburb of Hanzhong city, Shaanxi Province
Ningxia Soochow Agrochemical Limited Company

Contact:(+86）0512 6320 8190

Address:wujiang

Relevant to this article

Triterpene glycosides from the roots of Sanguisorba officinalis

Doi:10.1016/S0031-9422(01)00083-8
(2001)
Competitive antagonism of insect GABA receptors by iminopyridazine derivatives of GABA

Doi:10.1016/j.bmc.2012.07.049
(2012)
Straightforward Bienayme and copper catalyzed N-arylation sequence to access diverse 5H-pyrido[2′,1′:2,3]imidazo[4,5-b]indoles and analogues

Doi:10.1016/j.tet.2012.07.081
(2012)
Zinc-catalyzed functionalization of Si-H bonds with 2-furyl carbenoids through three-component coupling

Doi:10.1002/chem.201501155
(2015)
Hybrid stereoisomers of a compact molecular probe based on a jasmonic acid glucoside: Syntheses and biological evaluations

Doi:10.1016/j.bmc.2012.08.003
(2012)
Combined experimental and theoretical approaches to the molecular structure of 4-(1-formylnaphthalen-2-yloxy)phthalonitrile

Doi:10.1016/j.saa.2012.07.005
(2012)

Article Doi