Nucleophilic Desulfinylation of α-Fluoro-β-(alkoxy and silyloxy) Sulfoxides. Effects of the β-Oxy Substituent on Protonation, 1,2-Hydrogen Migration, and Nucleophile Addition to the Fluorocarbenoid Centers

DOI: 10.1246/bcsj.65.218

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Bulletin of the Chemical Society of Japan p. 218 - 227 (1992)

Update date:2022-07-29

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Authors:

Uno, Hidemitsu

Sakamoto, Katsuji

Suzuki, Hitomi

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Article abstract of DOI:10.1246/bcsj.65.218

Treatment of 2-(4-biphenylyl)-2-t-butyldimethylsilyloxy-1-chloro-1-fluoroethyl phenyl sulfoxide with PhMgBr resulted in the formation of a fluorostilbene derivative, a fluoro enol silyl ether and small amounts of 4-(fluoroacetyl)biphenyl, while a similar

Full text of DOI:10.1246/bcsj.65.218

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