Palladium-Catalyzed Coupling of Terminal Alkynes to the Free cis-Diol Metabolite Produced from the Oxidation of Bromobenzene by Pseudomonas putida: Synthesis of New Homochiral 3-Alkynyl cis-Cyclohexa-3,5-diene-1,2-diols

DOI: 10.1016/S0957-4166(00)80194-9

Source and publish data:

Tetrahedron Asymmetry p. 217 - 220 (1992)

Update date:2022-07-30

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Authors:

Hudlicky, Tomas

Boros, Eric E.

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Article abstract of DOI:10.1016/S0957-4166(00)80194-9

The free cis-diol metabolite (1) produced from the oxidation of bromobenzene by Pseudomonas putida underwent Pd(0)-catalyzed coupling with trimethylsilyl acetylene, phenylacetylene and 1-hexyne providing the novel homochiral (1S,2R)-3-alkynyl cis-cyclohex

Full text of DOI:10.1016/S0957-4166(00)80194-9

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