Preparation of allylsilanes by the olefination of carbonyl compounds using β-silylthioacetals

DOI: 10.1016/S0040-4039(98)00577-2

Source and publish data:

Tetrahedron Letters p. 3753 - 3756 (1998)

Update date:2022-07-29

Topics:

Authors:

Takeda, Takeshi

Watanabe, Mikako

Rahim, Abdur

Fujiwara, Tooru

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)00577-2

Titanocene(II)-promoted olefination of various carbonyl compounds using 1,1-bis(phenylthio)-2-triorganosilylethanes gave allylsilanes in good yields. γ-Alkoxy and alkylthio group substituted allylsilanes were also obtained by using carboxylic esters and thiolesters, respectively.

Full text of DOI:10.1016/S0040-4039(98)00577-2

Products guided by the article

Product name:Silane, [2-[4-(1,1-dimethylethyl)cyclohexylidene]ethyl]trimethyl-, (R)-

Cas No:140402-02-4

R&D Labs maybe for 140402-02-4

Daqing New Century Fine Chemical Co., Ltd.(expird)

Contact:010-57126694

Address:No.39, jinxing cun, honggang district
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.

Contact:+86-417-2927806

Address:yingkou
Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Synasia Inc

Contact:17316303296

Address:240 Amboy Ave
SHIFANG SUHONG CHEMICAL CO.,LTD

Contact:+86-838-2224563

Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China

Relevant to this article

Helical and network coordination polymers based on a novel C₂-symmetric ligand: SHG enhancement through specific metal coordination

Doi:10.1039/b316931f
(2004)
Design of a New and Highly Effective Chiral Auxiliary for Diels-Alder Reaction of 1-Aminodiene

Doi:10.1021/jo0302049
(2003)
Doi:10.1039/c39770000232
(1977)
Applications of EPR to a Study of the Hydrogenation of Ethene and Benzene over a Supported Pd Catalyst: Detection of Free Radicals on a Catalyst Surface

Doi:10.1039/ft9949003341
(1994)
Cross-coupling of grignard reagents with sulfonyl-activated sp³ carbon-nitrogen bonds

Doi:10.1002/adsc.201100285
(2011)
An improved synthesis of 4-azido-4-deoxy- and 4-amino-4-deoxy-α,α-trehalose and their epimers

Doi:10.1016/0008-6215(93)84215-R
(1993)

Article Doi