Preparation of allylsilanes by the olefination of carbonyl compounds using β-silylthioacetals

DOI: 10.1016/S0040-4039(98)00577-2

Source and publish data:

Tetrahedron Letters p. 3753 - 3756 (1998)

Update date:2022-07-29

Topics:

Authors:

Takeda, Takeshi

Watanabe, Mikako

Rahim, Abdur

Fujiwara, Tooru

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Article abstract of DOI:10.1016/S0040-4039(98)00577-2

Titanocene(II)-promoted olefination of various carbonyl compounds using 1,1-bis(phenylthio)-2-triorganosilylethanes gave allylsilanes in good yields. γ-Alkoxy and alkylthio group substituted allylsilanes were also obtained by using carboxylic esters and thiolesters, respectively.

Full text of DOI:10.1016/S0040-4039(98)00577-2

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