Ligand dependence of molybdenum-catalyzed alkylations. Molybdenum-isonitrile complexes as a new class of highly reactive alkylation catalysts

DOI: 10.1021/ja00182a018

Source and publish data:

Journal of the American Chemical Society p. 9590 - 9600 (1990)

Update date:2022-08-03

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Authors:

Trost, Barry M.

Merlic, Craig A.

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Article abstract of DOI:10.1021/ja00182a018

A series of molybdenum complexes bearing α-diimine, N,N′-diarylideneethylenediamine, and isonitrile ligands have been prepared and evaluated for their ability to catalyze alkylations by using allyl acetates and especially allyl sulfones. (bpy)Mo(CH_3<

Full text of DOI:10.1021/ja00182a018

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