Tetrahedron Letters p. 2751 - 2752 (1981)
Update date:2022-08-05
Topics:
Tsai, David Jieh Shyh
Matteson, Donald S.
Pinacol E-1-trimethylsilyl-1-propene-3-boronate reacts with aldehydes to form (+)-(R*, S*)-3-trimethylsilyl-4-hydroxy-1-alkenes, which can be deoxysilylated stereoselectively to either 98percent Z or 99percent E 1,3-dienes, including the separate components of the red bollworm moth pheromone.
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(2015)Doi:10.1039/c5dt02226f
(2015)Doi:10.1080/10426500701758421
(2008)Doi:10.2298/JSC111001023J
(2012)Doi:10.1021/jm00074a007
(1993)