Tetrahedron Letters p. 25 - 28 (1985)
Update date:2022-08-02
Topics: Steric Effects Solvent Effects Kinetic Isotope Effect (KIE) Arrhenius Plot Isotopic Labeling Hyperconjugation Deuterium (D)
Westaway, Kenneth Charles
Waszczylo, Zbigniew
Smith, Peter James
Rangappa, Kanchugarakoppal S.
Because the secondary alpha-deuterium kinetic isotope effects in some SN2 and E2 reactions are strongly concentration dependent, isotope effects measured at a single concentration could lead to erroneous conclusions about the mechanisms and tra
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(1955)
