LARGE CONCENTRATION EFFECTS ON THE MAGNITUDE OF SECONDARY ALPHA-DEUTERIUTERIUM KINETIC ISOTOPE EFFECTS

DOI: 10.1016/S0040-4039(00)98456-9

Source and publish data:

Tetrahedron Letters p. 25 - 28 (1985)

Update date:2022-08-02

Topics: Steric Effects Solvent Effects Kinetic Isotope Effect (KIE) Arrhenius Plot Isotopic Labeling Hyperconjugation Deuterium (D)

Authors:

Westaway, Kenneth Charles

Waszczylo, Zbigniew

Smith, Peter James

Rangappa, Kanchugarakoppal S.

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Article abstract of DOI:10.1016/S0040-4039(00)98456-9

Because the secondary alpha-deuterium kinetic isotope effects in some S_N2 and E2 reactions are strongly concentration dependent, isotope effects measured at a single concentration could lead to erroneous conclusions about the mechanisms and tra

Full text of DOI:10.1016/S0040-4039(00)98456-9

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