Tetrahedron Letters p. 25 - 28 (1985)
Update date:2022-08-02
Topics: Steric Effects Solvent Effects Kinetic Isotope Effect (KIE) Arrhenius Plot Isotopic Labeling Hyperconjugation Deuterium (D)
Westaway, Kenneth Charles
Waszczylo, Zbigniew
Smith, Peter James
Rangappa, Kanchugarakoppal S.
Because the secondary alpha-deuterium kinetic isotope effects in some SN2 and E2 reactions are strongly concentration dependent, isotope effects measured at a single concentration could lead to erroneous conclusions about the mechanisms and tra
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(2012)Doi:10.1039/c2ob26456k
(2012)Doi:10.1016/S0040-4039(00)84538-4
(1986)Doi:10.1002/hlca.19550380725
(1955)
