CONVERSION OF 2-IODOANILINE INTO (Z)-3-METHYLENE-2,3-DIHYDROINDOLE DERIVATIVES

DOI: 10.3987/COM-91-5850

Source and publish data:

Heterocycles p. 2365 - 2372 (1991)

Update date:2022-08-02

Topics:

Authors:

Luo, Fen-Tair

Wang, Ren-Tzong

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Article abstract of DOI:10.3987/COM-91-5850

Treatment of N-(2-iodophenyl)-N-2-propynyl-p-tolylsulfonamide with various organozinc chlorides in the presence of palladium acetate, triphenylphosphine, and 1 equiv. of triethylamine in tetrahydrofuran gives (Z)-3-alkylidene-2,3-dihydroindoles via intramolecular Heck-type reaction and successive cross coupling reactions.

Full text of DOI:10.3987/COM-91-5850

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