Journal of the Chemical Society, Dalton Transactions p. 379 - 384 (1992)
Update date:2022-07-30
Topics:
Kwiatkowski, Marek
Bandoli, Giuliano
The condensation fo N-acylated derivatives of o-aminocarbonyl aromatic compounds with the precursor 7-amino-4-methyl-5-azahept-3-en-2-one has been found to depend on the acidity of the amide proton and the nature of the substituent on the carbonyl carbon atom.Three new quadridentate Schiff-base ligands and their nickel(II) complexes having a pendant N-acetyl or N-trifluoroacetyl group have been obtained and characterized by spectroscopic techniques.A very unusual temperature-dependent proton NMR spectrum has been found for <4-methyl-9-(o-trifluoroacetylaminophenyl)-5,8-diazadeca-3,8-dien-2-onato(2-)>nickel(II) indicating a substantial energy barrier for enantiomer interconversion of the chiral complex molecule at moderate temperature.The crystal and molecular structure of this complex has been determined and shows that a fluorine-nickel interaction may be responsible for the inhibited enantiomer interconversion in N-trifluoroacetyl substituted nickel complexes.Crystallographic data: space group P21/c, a = 9.057(2), b = 13.769(4), c = 14.664(4) Angstroem, β = 108.43(2) deg, final R = 0.0434.
View MoreShenyang NovPharm Technology Co., Ltd.
Contact:.+86-24-24165786
Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.
Zhongshan Haihong Medicine Co., Ltd.
Contact:86-0760-86925778 （0）18824993998
Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Contact:0086 371 65711996
Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Shanghai Run-Biotech Co., Ltd.
website:http://www.run-biotech.com
Contact:+86-21-31576854/57171705 / 57171706
Address:second floor, building 3, No.999, jiangyue Road, minghang District, Shanghai, China
Contact:+86-710-3516804
Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei
Doi:10.1016/j.bmc.2012.08.031
(2012)Doi:10.1016/j.bmcl.2012.09.029
(2012)Doi:10.1021/jm301188x
(2012)Doi:10.1134/S1070428012090229
()Doi:10.1016/j.tetlet.2009.10.112
(2010)Doi:10.1016/0022-328X(92)80003-G
(1992)
