Die Reaktion von Silyl-bis(trifluormethansulfonaten) mit Diazoessigestern und Diazomethyl-ketonen

DOI: 10.1016/0022-328X(92)80001-E

Source and publish data:

Journal of Organometallic Chemistry p. 253 - 272 (1992)

Update date:2022-08-02

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Authors:

Fronda, Antonio

Krebs, Fred

Daucher, Birgit

Werle, Thorsten

Maas, Gerhard

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Article abstract of DOI:10.1016/0022-328X(92)80001-E

Equimolar amounts of diazoacetates and dialkylsilyl-bis(trifluoromethanesulfonates) (alkyl = methyl, i-propyl, t-butyl) in the presence of a tertiary amine yield <(trifluoromethylsulfonyloxy)-dialkylsilyl>diazoacetates, whereas a 2/1 molar ratio of the re

Full text of DOI:10.1016/0022-328X(92)80001-E

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