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Stereoselective Nucleophilic Addition to Conformationally Constrained Piperidines. An Efficient Route to 2-Axial-6-Equatorial Disubstituted Piperidines.

DOI: 10.1016/S0040-4039(00)91562-4

Source and publish data:

Tetrahedron Letters p. 867 - 870 (1992)

Update date:2022-08-05

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Authors:

Meyers, A. I.Meyers, A. I.

Shawe, Thomas T.Shawe, Thomas T.

Gottlieb, LeviGottlieb, Levi

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Article abstract of DOI:10.1016/S0040-4039(00)91562-4

Addition of RMgX to 2-methoxy-4-tert-butylpiperidine formamidine in dichloromethane or ether gives good to excellent yields of axial product.

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Full text of DOI:10.1016/S0040-4039(00)91562-4

Products guided by the article

Product name:tert-Butyl-[1-(4-tert-butyl-3,4-dihydro-2H-pyridin-1-yl)-meth-(Z)-ylidene]-amine

Cas No:141069-14-9

141069-14-9

R&D Labs maybe for 141069-14-9

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