On the palladium catalyzed reaction of methallyl-1,1-diacetate with cyclic β-ketoesters. Intervention of hidden mechanisms

DOI: 10.1016/S0040-4039(00)91632-0

Source and publish data:

Tetrahedron Letters p. 1403 - 1406 (1992)

Update date:2022-08-03

Topics:

Authors:

Gravel Gravel

Benoit Benoit

Kumanovic

Sivaramakrishnan

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Article abstract of DOI:10.1016/S0040-4039(00)91632-0

Palladium(O) catalysis in the title reaction causes the release of methacrolein which competes effectively with the π-allyl species in product formation, a bicycloannulated derivative, when DBU is used as base.

Full text of DOI:10.1016/S0040-4039(00)91632-0

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