Reaction of α-Diketones with 2-Amino Alcohols. Intramolecular Competitive 6-exo-trig vs 5-endo-trig Processes. A Systematic and Kinetic Study

DOI: 10.1021/jo00034a046

Source and publish data:

Journal of Organic Chemistry p. 2446 - 2454 (1992)

Update date:2022-08-06

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Authors:

Alcaide, Benito

Plumet, Joaquin

Rodriguez-Campos, Ignacio M.

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Article abstract of DOI:10.1021/jo00034a046

2-Aminoethanol and C-substituted derivatives 1 react with diacetyl, benzil, and 1-phenyl-1,2-propanedione, models of α-diketones 2 to give with remarkable regio- and stereoselectivity 2-hydroxy-5,6-dihydro-2H-1,4-oxazines 3, cis-octahydro<1,4>oxazino<3,2-

Full text of DOI:10.1021/jo00034a046

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