Asymmetric Synthesis of Functionalised Pyrrolidines. Highly Diastereoselective Cyclisations Mediated by Sulfide and Sulfoxide Ligands

DOI: 10.1039/c39920000335

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 335 - 337 (1992)

Update date:2022-08-05

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Authors:

Davies, Ian W.

Gallagher, Timothy

Lamont, R. Brian

Scopes, David I.C.

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Article abstract of DOI:10.1039/c39920000335

Silver(I)-catalysed cyclisation of sulfide 1b and sulfoxides 4 and 5 to give the corresponding 2-vinylpyrrolidines 2b, 6a and 7a, respectively proceeds with a high ( up to 99 percent diastereoisomeric excess) level of diastereoselectivity; in all of these

Full text of DOI:10.1039/c39920000335

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