Asymmetric Synthesis of Functionalised Pyrrolidines. Highly Diastereoselective Cyclisations Mediated by Sulfide and Sulfoxide Ligands

DOI: 10.1039/c39920000335

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 335 - 337 (1992)

Update date:2022-08-05

Topics:

Authors:

Davies, Ian W.

Gallagher, Timothy

Lamont, R. Brian

Scopes, David I.C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000335

Silver(I)-catalysed cyclisation of sulfide 1b and sulfoxides 4 and 5 to give the corresponding 2-vinylpyrrolidines 2b, 6a and 7a, respectively proceeds with a high ( up to 99 percent diastereoisomeric excess) level of diastereoselectivity; in all of these

Full text of DOI:10.1039/c39920000335

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(S)-1-[(R)-2-((S)-Benzenesulfinyl)-1-phenyl-ethyl]-2-vinyl-pyrrolidine

Cas No:141196-16-9

R&D Labs maybe for 141196-16-9

Shreeji pharma international

Contact:0091-265-2313036

Address:311, ATLANTIS HEIGHTS SARABHAI MAIN ROAD,VADIWADI ,VADODARA
Linyi Shengxin Pharmaceutical R&D Co., Ltd

Contact:+86-18653953873

Address:West First of Yufeng Road, Yishui County
Wuhan Konberd Biotech Co., Ltd.

Contact:+86-27-87205925

Address:NO.666, Gaoxin Road, Eastlake High-tech zone
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,

Relevant to this article

Selective Reversible and Irreversible Ligands for the κ Opioid Receptor

Doi:10.1021/jm00090a015
(1992)
Theoretical and Experimental Optimization of a New Amino Phosphite Ligand Library for Asymmetric Palladium-Catalyzed Allylic Substitution

Doi:10.1002/cctc.201500873
(2015)
Stereoselective hydrogen-transfer reactions involving acyclic radicals. A study of radical conformations using semiempirical calculations

Doi:10.1021/ja00038a072
(1992)
The morita-baylis-hillman reaction of chiral highly oxygenated cyclopent-2-enones

Doi:10.1002/hlca.201200421
(2012)
Facile and efficient synthesis of (r)-4-(benzyloxy)-3-methylbutanenitrile: Toward developing a versatile chiral building block

Doi:10.1002/cjoc.201200517
(2012)
Synthesis and glycosidase inhibitory profiles of functionalised morpholines and oxazepanes

Doi:10.1016/j.bmc.2011.07.019
(2011)

Article Doi