Palladium-catalyzed reduction of an allylic amine: A formal access to both diastereoisomers of cyclopentenyl glycine

DOI: 10.1016/S0040-4039(00)91600-9

Source and publish data:

Tetrahedron Letters p. 1277 - 1280 (1992)

Update date:2022-08-04

Topics:

Authors:

Borugeois-Cury

Doan Doan

Gore Gore

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Article abstract of DOI:10.1016/S0040-4039(00)91600-9

The easily accessible bicyclic amines 3 (exo or endo) are regioselectively transformed to the methyl esters of the diastereoisomers (1c or 1d) of N-benzyl cyclopentenylglycine by reaction with hydride donors (mainly NaBH₃CN) in the presence of

Full text of DOI:10.1016/S0040-4039(00)91600-9

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