Remote Oxidation of Perhydrophenanthrenes by Template-Directed Hydrogen Atom Abstraction

DOI: 10.1021/jo00040a050

Source and publish data:

Journal of Organic Chemistry p. 4005 - 4013 (1992)

Update date:2022-07-30

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Authors:

Kerwin, Sean Michael

Heathcock, Clayton H.

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Article abstract of DOI:10.1021/jo00040a050

The use of Breslow's remote functionalization paradigm for installation of an axial C-7 hydroxy group into a perhydrophenanthrene nucleus, with a view toward synthesis of bruceantin (1), has been investigated.The substrates that were evaluated were 9a-c,

Full text of DOI:10.1021/jo00040a050

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