SYNTHESE CYCLOPROPENIQUE TOTALE D'UN TRIQUINANE NATUREL LINEAIRE, LE (+/-)-HIRSUTENE

DOI: 10.1016/S0040-4039(00)99431-0

Source and publish data:

Tetrahedron Letters p. 3529 - 3532 (1989)

Update date:2022-08-03

Topics: Synthese cyclopropenique totale

Authors:

Franck-Neumann, M.

Miesch, M.

Lacroix, E.

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Article abstract of DOI:10.1016/S0040-4039(00)99431-0

The cycloaddition of enamines with electrophilic gem-dimethylcyclopropenes followed by solvolytic ring cleavage of the 2-amino bicyclo <2.1.0> pentane adducts, leads to gem-dimethylcyclopentene derivatives.This novel reaction sequence is illustrated by th

Full text of DOI:10.1016/S0040-4039(00)99431-0

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Product name:Cyclopropanecarboxylic acid, 3-[4-(benzoyloxy)-1,3a,4,5,6,6a-hexahydro-3a-methyl-3-(4-morpholinyl)- 2-pentalenyl]-2,2-dimethyl-, methyl ester

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