REGIOSELECTIVE CARBON-CARBON BOND FORMATION AT C2 OF 1,3-THIAZOLE BY REACTION OF N-ETHOXYCARBONYLTHIAZOLIUM CHLORIDE WITH C-NUCLEOPHILES

DOI: 10.1016/S0040-4039(01)91094-9

Source and publish data:

Tetrahedron Letters p. 3633 - 3636 (1984)

Update date:2022-08-02

Topics:

Authors:

Dondoni, Alessandro

Dall'Occo, Tiziano

Fantin, Giancarlo

Fogagnolo, Marco

Medici, Alessandro

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Article abstract of DOI:10.1016/S0040-4039(01)91094-9

N-Ethoxycarbonylthiazolium chloride generated in situ from 1,3-thiazole and ethyl chloroformate, treated with lithium carbanions of esters, Grignard reagents, silyl enol ethers and esters, undergo nucleophilic addition at C2 affording the corresponding 2-substituted N-ethoxycarbonylthiazolines.

Full text of DOI:10.1016/S0040-4039(01)91094-9

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