Diels-Alder Cycloadditions Using Nucleophilic 3-(p-Tolylthio)-2-pyrone. Regiocontrolled and Stereocontrolled Synthesis of Unsaturated, Bridged, Bicyclic Lactones

DOI: 10.1021/jo00041a009

Source and publish data:

Journal of Organic Chemistry p. 4083 - 4088 (1992)

Update date:2022-08-05

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Authors:

Posner, Gary H.

Nelson, Todd D.

Kinter, Chris M.

Johnson, Neil

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Article abstract of DOI:10.1021/jo00041a009

Captodative 3-(tolylthio)-2-pyrone (1) is shown to be reactive as a nucleophilic diene undergoing 2 + 4-cycloadditions with various electrophilic alkenes under sufficiently mild thermal conditions ( View More

Full text of DOI:10.1021/jo00041a009

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