THE GENERATION OF CARBONYL COMPOUNDS FROM ACETALS AND KETALS BY IODOTRICHLOROSILANE (ITCS)

DOI: 10.1016/S0040-4039(00)91700-3

Source and publish data:

Tetrahedron Letters p. 1657 - 1660 (1992)

Update date:2022-08-04

Topics:

Authors:

Elmorsy, Saad S.

Bhatt, M. V.

Pelter, Andrew

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Article abstract of DOI:10.1016/S0040-4039(00)91700-3

Cheap and readily available iodotrichlorosilane (SiCl4/NaI) readily regenerates aldehydes and ketones from cyclic and acyclic acetals and ketals, in 20-60 min at ambient temperature.The reaction is highly chemoselective as phenolic ethers and esters are not cleaved.The pathway for the process is unlike any previously proposed.

Full text of DOI:10.1016/S0040-4039(00)91700-3

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