Tetrahedron Letters p. 1657 - 1660 (1992)
Update date:2022-08-04
Topics:
Elmorsy, Saad S.
Bhatt, M. V.
Pelter, Andrew
Cheap and readily available iodotrichlorosilane (SiCl4/NaI) readily regenerates aldehydes and ketones from cyclic and acyclic acetals and ketals, in 20-60 min at ambient temperature.The reaction is highly chemoselective as phenolic ethers and esters are not cleaved.The pathway for the process is unlike any previously proposed.
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Doi:10.1002/hlca.201200380
(2012)Doi:10.1002/cmdc.201900180
(2019)Doi:10.1080/00397919208019303
(1992)Doi:10.1021/ol303154k
(2013)Doi:10.1016/0040-4039(92)88131-N
(1992)Doi:10.1039/c2cc35974j
(2013)
