Tetrahedron Letters p. 155 - 158 (1995)
Update date:2022-08-04
Topics:
Gregory, J. A.
Jennings, A. J.
Joiner, G. F.
King, F. D.
Rahman, S. K.
The novel synthesis of a series of 3,9-diazabicyclo<3.3.1>nonan-7-amines (4) is reported via an alane reduction of a key intermediate oxime (8).The stereoselectivity of the reduction is highly dependent on the size of the 3-aza substituent.
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