AN ATTEMPT ON THE SYNTHESIS OF THE CLAVAM SKELETON FROM GLYCALS AND ISOCYANATES

DOI: 10.1016/S0040-4020(01)90975-5

Source and publish data:

Tetrahedron p. 2935 - 2950 (1992)

Update date:2022-08-02

Topics:

Authors:

Chmielewski, M.

Grodner, J.

Fudong, Wang

Urbanczyk-Lipkowska, Z.

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Article abstract of DOI:10.1016/S0040-4020(01)90975-5

N-Protected 2-C:1-N-carbonyl-2-deoxy-glycopyranosylamines 12, 13, and 16 were subjected to the two-step oxidation to afford dicarboxylic acids 20, 21, and 30.Decarboxylation of the group located in a malonyl system with the β-lactam carbonyl group failed

Full text of DOI:10.1016/S0040-4020(01)90975-5

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Product name:3,4,6-tri-O-benzyl-N-t-butyldimethylsilyl-2-C:1-N-carbonyl-2-deoxy-α-D-galactopyranosylamine

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