1,3-Dipolar cycloaddition to the Fe-N=C fragment. 14. Aromatic isothiocyanates as dipolarophiles. Reversible formation of novel [3.2.2] bicyclic double isocyanide insertion products. Thermodynamics of isocyanide deinsertion reactions

DOI: 10.1021/om00019a044

Source and publish data:

Organometallics p. 2825 - 2832 (1994)

Update date:2022-08-02

Topics:

Authors:

Feiken, Nantko

Frühauf, Hans-Werner

Vrieze, Kees

Fraanje, Jan

Goubitz, Kees

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00019a044

The 1,3-dipolar cycloaddition reaction of Fe((2,6-xylyl)NC)₃(i-PrDAB) (7) with para-substituted phenyl isothiocyanates (R″C₆H₄NCS; R″ = H (a), Me (b), OMe (c), NO₂ (d)) is followed by one or two isonitrile inser

Full text of DOI:10.1021/om00019a044

Products guided by the article

Product name:iron(2,6-xylyl-isocyanide)3(i-Pr-DAB)

Cas No:141647-13-4

R&D Labs maybe for 141647-13-4

Shochem(Shanghai) Co., Ltd

website:http://www.shochem.com

Contact:021-50800795

Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Shanghai Hanshare Industry Co.,Ltd.

Contact:86 21 20960688

Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
zhuzhou zhongle chemical co. ltd.

Contact:+86-0731 28228409

Address:Zhuzhou, Hunan, China
KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao

Relevant to this article

Metal Ion Controlled Addition to α,β-Dialkoxy Carbonyl Compounds

Doi:10.1021/jo00203a040
(1985)
Acetylenic silyl ketone as polysynthetic equivalent of useful building blocks in organic synthesis

Doi:10.1016/S0040-4020(01)00578-6
(2001)
Synthesis and anti-avian influenza virus (H5N1) evaluation of some novel nicotinonitriles and their N-acylic nucleosides

Doi:10.1002/jhet.966
(2012)
Design and synthesis of new N-substituted amino methyl-[1,2,3] triazolyl moieties of fluoroquinolones as antibacterial agents

Doi:10.1007/s00044-012-0394-2
(2013)
Reactions of 3-carene, limonene, and α-pinene nitrosochlorides with imidazole, benzotriazole, and indole

Doi:10.1007/s11172-012-0085-7
()
Stereoselective glycosylations by nitrosyl tetrafluoroborate-catalyzed activation of glycosyl trichloroacetimidate derivatives

Doi:10.1055/S-0032-1317135
(2012)

Article Doi