1,3-Dipolar cycloaddition to the Fe-N=C fragment. 14. Aromatic isothiocyanates as dipolarophiles. Reversible formation of novel [3.2.2] bicyclic double isocyanide insertion products. Thermodynamics of isocyanide deinsertion reactions

DOI: 10.1021/om00019a044

Source and publish data:

Organometallics p. 2825 - 2832 (1994)

Update date:2022-08-02

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Authors:

Feiken, Nantko

Frühauf, Hans-Werner

Vrieze, Kees

Fraanje, Jan

Goubitz, Kees

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Article abstract of DOI:10.1021/om00019a044

The 1,3-dipolar cycloaddition reaction of Fe((2,6-xylyl)NC)₃(i-PrDAB) (7) with para-substituted phenyl isothiocyanates (R″C₆H₄NCS; R″ = H (a), Me (b), OMe (c), NO₂ (d)) is followed by one or two isonitrile inser

Full text of DOI:10.1021/om00019a044

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