Journal of Organic Chemistry p. 2059 - 2066 (2017)
Update date:2022-08-04
Topics:
Zhang, Wen-Man
Dai, Jian-Jun
Xu, Jun
Xu, Hua-Jian
A photoredox catalytic method has been developed for the direct C2 alkylation of pyridine N-oxides. This reaction is compatible with a range of synthetically relevant functional groups for providing efficient synthesis of a variety of C2-alkylated pyridine N-oxides under mild conditions. Mechanistic studies are consistent with the generation of a radical intermediate along the reaction pathway.
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