X-ray structure and physical properties of the oxo-bridged complex [(F8-TPP)Fe-O-Cu(TMPA)]+, F8-TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-), TMPA = tris(2-pyridylmethyl)amine: Modeling the cytochrome c oxidase Fe-Cu heterodinu

DOI: 10.1021/ja00090a023

Source and publish data:

Journal of the American Chemical Society p. 4753 - 4763 (1994)

Update date:2022-07-29

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Authors:

Karlin, Kenneth D.

Nanthakumar, Alaganandan

Fox, Stephen

Murthy, Narasimha N.

Ravi, Natarajan

Huynh, Boi Hanh

Orosz, Robert D.

Day, Edmund P.

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Article abstract of DOI:10.1021/ja00090a023

The iron/copper heterodinuclear center in cytochrome c oxidases has attracted the interest of inorganic chemists since this is the site of dioxygen (O₂) four-electron four-proton reduction to water by the reduced enzyme, while the oxidized ("re

Full text of DOI:10.1021/ja00090a023

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