Journal of Organic Chemistry p. 3583 - 3589 (1992)
Update date:2022-08-04
Topics:
Pearson, Anthony J.
Park, Jewn G.
Zhu, Ping Y.
Reactions of <(cyclopentadienyl)(1,3-dichlorobenzene)M>+ PF6- complexes (M = Fe, Ru) with phenoxide nucleophiles were found to proceed with excellent selectivity under mild conditions to give products of monosubstitution.Using aminophenoxides, a preference for O-arylation was observed, while amino alcohols such as prolinol react selectively on nitrogen.Methodology for sequential selective displacement of both chlorides by different nucleophiles is reported.
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