Journal of Organic Chemistry p. 3583 - 3589 (1992)
Update date:2022-08-04
Topics:
Pearson, Anthony J.
Park, Jewn G.
Zhu, Ping Y.
Reactions of <(cyclopentadienyl)(1,3-dichlorobenzene)M>+ PF6- complexes (M = Fe, Ru) with phenoxide nucleophiles were found to proceed with excellent selectivity under mild conditions to give products of monosubstitution.Using aminophenoxides, a preference for O-arylation was observed, while amino alcohols such as prolinol react selectively on nitrogen.Methodology for sequential selective displacement of both chlorides by different nucleophiles is reported.
View MoreContact:86 513 85512619
Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China
Suzhou Howsine Biological Technology Co.,Ltd(expird)
website:http://www.howsine.com
Contact:86-512-67262751
Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
jiangsu haian chemical co.,ltd.
Contact:86-513-15851283853
Address:No.99,Changjiang West Road,Haian County,Jiangsu Province,China
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd
Contact:+86-533-5415882
Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Taizhou Sunny Chemical Co.,Ltd
Contact:+86-523-86920899 +86-13951172783
Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
Doi:10.1002/asia.201200859
(2013)Doi:10.1016/j.tetlet.2012.11.079
(2013)Doi:10.1021/ol401403n
(2013)Doi:10.1021/ol303531m
(2013)Doi:10.1016/j.bmcl.2012.11.051
(2013)Doi:10.1002/adsc.201801510
(2019)
