Journal of Organic Chemistry p. 3583 - 3589 (1992)
Update date:2022-08-04
Topics:
Pearson, Anthony J.
Park, Jewn G.
Zhu, Ping Y.
Reactions of <(cyclopentadienyl)(1,3-dichlorobenzene)M>+ PF6- complexes (M = Fe, Ru) with phenoxide nucleophiles were found to proceed with excellent selectivity under mild conditions to give products of monosubstitution.Using aminophenoxides, a preference for O-arylation was observed, while amino alcohols such as prolinol react selectively on nitrogen.Methodology for sequential selective displacement of both chlorides by different nucleophiles is reported.
View MoreZhangjiagang Jianing Import & Export Co.,Ltd.
Contact:086-512-55379012 13913607595
Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
jintan yufan Medicine Raw materials Co.,Ltd.(expird)
Contact:86-519-82808282
Address:6th,Jincheng Huangzhuang
Suzhou Jingye Medicine & Chemical Co., Ltd
Contact:+86-512-66658588
Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
website:http://www.truewingroup.com
Contact:86-311-66699812
Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
Contact:13120882795；+86-21-34621078;+86-021-31122318
Address:Suite 2,No.2715 Longwu Road
Doi:10.1002/asia.201200859
(2013)Doi:10.1016/j.tetlet.2012.11.079
(2013)Doi:10.1021/ol401403n
(2013)Doi:10.1021/ol303531m
(2013)Doi:10.1016/j.bmcl.2012.11.051
(2013)Doi:10.1002/adsc.201801510
(2019)
