Tandem Intramolecular Michael Addition/Aldol Condensation or Acylation Applied to D-Glucose-Derived Substrates: Preparation of Enantiomeric Octahydronaphthalenone Derivatives Equipped with C- and O-Functionalities

DOI: 10.1021/jo00042a034

Source and publish data:

Journal of Organic Chemistry p. 4496 - 4506 (1992)

Update date:2022-08-02

Topics:

Authors:

Tadano, Kin-ichi

Nagashima, Kensuke

Ueno, Yoshihide

Ogawa, Seiichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00042a034

An enantiomerically pure (1,2-isopropylidenedioxy)tetrahydrofuran derivative, 9, bearing acetonyl and propionaldehyde side chains smoothly underwent aldol cyclization under basic conditions.The major product was the cis-aldol 21S, accompanied by the trans

Full text of DOI:10.1021/jo00042a034

Products guided by the article

Product name:(4aS,6S,6aS,7aR,10aR,10bR,10cS)-6-Benzyloxy-9,9-dimethyl-4a,5,6,6a,7a,10a,10b,10c-octahydro-4H-7,8,10-trioxa-pentaleno[1,2-a]naphthalen-1-one

Cas No:142133-46-8

R&D Labs maybe for 142133-46-8

Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China
GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China

Relevant to this article

A green metal-free "one-pot" microwave assisted synthesis of 1,4-dihydrochromene triazoles

Doi:10.1039/d1ra01169c
(2021)
Synthesis and biological activities of novel trifluoromethylpyridine amide derivatives containing sulfur moieties

Doi:10.1039/d0ra07301f
(2020)
Cp^?Co(III)-catalyzed direct functionalization of aromatic C-H bonds with α-diazomalonates

Doi:10.1016/j.tetlet.2015.05.025
(2015)
Dioxirane oxidation of 2-Aryl-1-vinyl-1, 1-diphosphane dioxide: A convenient approach for the synthesis of novel 1,2-epoxy-2-aryl ethylgembisphosphonates

Doi:10.1002/hc.21084
(2013)
Preparation and Reactions of Thiazole-fused 3-Sulfolenes. Useful Precursors to o-Dimethylene Thiazoles

Doi:10.1016/S0040-4039(00)74689-2
(1992)
Coordination Modes, Oxidation, and Protonation Levels of 2,6-Pyridinediimine and 2,2′:6′,2′-Terpyridine Ligands in New Complexes of Cobalt, Zirconium, and Ruthenium. An Experimental and Density Functional Theory Computational Study

Doi:10.1021/acs.inorgchem.8b01949
(2019)

Article Doi