Synthesis of allyl 6-O-(3-deoxy-α- and -β-D-manno-oct-2-ulopyranosylonic acid)-(1->6)-2-deoxy-2--β-D-glucopyranoside 4-phosphate and of the copolymer of the α anomer with acrylamide

Article abstract of DOI:10.1016/S0008-6215(00)90547-0

The title disaccharides were synthesized by mercuric cyanide-catalyzed condensation of methyl (4,5,7,8-tetra-O-acetyl-3-deoxy-α-D-manno-oct-2-ulopyranosyl bromide)onate and allyl 2-<(3R)-3-acetoxy-tetradecanamido>-3-O-benzyl-2-deoxy-β-D-glucopyranoside, f