The Synthesis of Octahedral Mixed Bis-alkyne and Alkyne-alkene Complexes of Tungsten

DOI: 10.1039/c39920001069

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1069 - 1070 (1992)

Update date:2022-08-02

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Authors:

Clark, George R.

Nielson, Alastair J.

Rae, A. David

Rickard, Clifton E. F.

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Article abstract of DOI:10.1039/c39920001069

Replacement of a phosphine ligand in by PhC<*>CPh, PhC<*>CH and HC<*>CH, or reduction of in the presence of MeC2Me and Me(CH2)2C2Me yields mixed bis-alkyne complexes; under ethylene or propene the reduction reactions afford mixed alkyne-alkene complexes, and the structure of has been confirmed by X-ray crystallography.

Full text of DOI:10.1039/c39920001069

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