Carbon-sulfur bond formation by reductive elimination of gold(iii) thiolates

DOI: 10.1039/c8dt00906f

Source and publish data:

Dalton Transactions p. 6333 - 6343 (2018)

Update date:2022-09-26

Topics:

Authors:

Currie, Lucy

Rocchigiani, Luca

Hughes, David L.

Bochmann, Manfred

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Article abstract of DOI:10.1039/c8dt00906f

Whereas the reaction of the gold(iii) pincer complex (C^N^C)AuCl with 1-adamantyl thiol (AdSH) in the presence of base affords (C^N^C)AuSAd, the same reaction in the absence of base leads to formation of aryl thioethers as the products of reductive elimin

Full text of DOI:10.1039/c8dt00906f

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Product name:[(2,6-bis(4-tBuC₆H₃)₂pyridine dianion)Au(dimethylsulfide)][N₂H(B(C₆F₅)₃)₂]

Cas No:1422722-27-7

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